SOFT MATTER RESEARCH
In the soft matter area, we focus on understanding glass and
jamming transitions in granular materials, dense colloidal suspensions,
foams, and model systems, in which the structural and stress
relaxation times diverge (in the absence of crystallization) when various control parameters such as temperature, density, and applied stress are tuned. We employ a combination of theoretical (master-equation approaches and statistical mechanics) and computational (molecular dynamics and Monte Carlo simulations) techniques to understand fundamental aspects of glass and jamming transitions.
Ongoing projects include:
1. Quasi-one dimensional models for glassy behavior
Dense colloidal suspensions undergo a glass transition as they are compressed above the packing fraction φg = 0.58. For φ> φg, the viscosity diverges at such a stupendous rate that it becomes experimentally impossible to measure. The nature of the viscosity divergence (or equivalently the vanishing of particle diffusion) as φ → φg is one of the fundamental open questions in soft matter research. Related questions include at which packing fraction does the viscosity truly diverge, does it depend on quench rate, and what is the form of the divergence? To address these questions, we have developed a quasi-one-dimensional model, where hard rods diffuse through a series of connected loops and intersections. The advantage of this model is that it displays many of the hallmarks of the glass transition, yet the form of the divergence of the structural relaxation with increasing packing fraction can be calculated analytically. The analytical technique relies on a master equation approach, where we define the relevant microstates of the system, and then relate entropic bottlenecks to transition probabilities.
(a) P. Pal, C. S. O'Hern, J. Blawzdziewicz, E. R. Dufresne, and R. Stinchcombe, ``A minimal model for kinetic arrest'', Phys. Rev. E 78 (2008) 011111.
(b) P. Pal, C. S. O'Hern, and J. Blawzdziewicz, "Quasi-one-dimensional models for glassy dynamics," submitted to Physical Review E (2010).
2. The connection between percolation in configuration space
and glassy dynamics
We have identified a link between the glass transition and percolation of regions of mobility in configuration space. We find that many hallmarks of glassy dynamics, for example stretched-exponential response functions and a diverging structural relaxation time, are consequences of the critical properties of mean-field percolation. Specific predictions of the percolation model include the range of possible stretching exponents 1/3 ≤ β ≤ 1 and the functional dependence of the structural relaxation time τα and exponent β on temperature, density, and wave number.
(a) G. Lois, J. Blawzdziewicz, and C. S. O'Hern, ``A percolation model for glassy dynamics in disordered materials'', Phys. Rev. Lett. 102 (2009) 015702.
(b) G. Lois, J. Blawzdziewicz, and C. S. O'Hern, ``Protein folding on rugged energy landscapes: Conformational diffusion on a fractal network'', submitted to Phys. Rev. E (2010).
3. Statistical mechanics of static and slowly flowing granular media
There is currently no fundamental understanding of how to uniquely characterize the state of a dense granular system using macroscopic descriptors. In this proposed research, we seek such a description using a systematic, bottom-up approach. We propose a set of coordinated experiments, numerical simulations, and theoretical studies to provide predictive and quantitative descriptions of the structural and mechanical properties of static and slowly driven granular materials. We will decompose granular packings into a collection of subsystems and measure their statistics. We will then correlate the statistics of the subsystems with the measured structural and mechanical properties of the packings, such as, packing fraction, contact number, radial distribution function, and elastic moduli. These correlations will provide a basis for a predictive theory of static and slowly driven granular materials. In contrast to previously employed quasi-thermodynamic approaches, we advocate using a master-equation approach with no built-in assumptions about the packings
probabilities. Instead, we will develop a novel method to calculate the packing probabilities of large systems in terms of the statistics of small subsystems. This work will be done in collaboration with Prof. Jerzy Blawzdziewicz (Mechanical Engineering, Physics) and Prof. Mark Shattuck (Physics, Benjamin Levich Institute and CCNY).
(a) G.-J. Gao, J. Blawzdziewicz, and C. S. O'Hern, ``Geometrical families of mechanically stable granular packings,'' Phys. Rev. E 80 (2009) 061303.
(b) G.-J. Gao, J. Blawzdziewicz, C. S. O'Hern, and M. Shattuck, ``Experimental demonstration of nonuniform frequency distributions of mechanically stable granular packings'', Phys. Rev. E 80 (2009) 061304.
4. Jamming in systems composed of anisotropic particles and with polymer constraints
More than ten years ago, Andrea Liu (Physics, UPenn) and Sid Nagel (Physics, UChicago) introduced the provocative idea that jamming behavior in athermal systems such as granular media and foams has the same physical origin as glass transitions in thermal systems. After a decade of intense study, there is evidence that such a link exists at least for model particulate systems composed of spherical particles. Moreover, we now have a deeper understanding of the vibrational modes and structural and mechanical properties for amorphous packings of spherical particles.
However, there has been a relative paucity of work aimed at investigating the structural, mechanical, and dynamical properties of systems composed of objects with more realistic shapes and more complex microstructures. In this research area, we will take the field of jamming in two new directions that will enable even closer contact with physical experiments over a wider range of systems. We will perform novel theoretical and computational studies of (1) the
packing, slow dynamics, and mechanical response of systems composed of frictionless, nonspherical particles and (2) the structure and dynamics of polymer packings. These studies will lead to a deeper understanding of soft matter systems such as granular media, foams, emulsions, and colloids that undergo jamming and glass transitions. Further, it will have a transformative impact on the research communities that study polymer collapse and protein folding since the tools and concepts from jamming and packing studies have not yet been utilized in these areas.
(a) M. Mailman, C. F. Schreck, B. Chakraborty, and C. S. O'Hern, ``Jamming in systems composed of ellipse-shaped particles'', Phys. Rev. Lett. 102 (2009) 255501.
(b) C. Schreck and C. S. O’Hern, “A comparison of jamming behavior in systems composed of dimer and ellipsoidal shaped particles,” submitted to Soft Matter (2010).